Polypropylene Homopolymer (PPH) is a type of polypropylene available in a semi-crystalline solid form, containing only propylene monomer. It is recognized for its high strength-to-weight ratio, stiffness, and strong performance characteristics. PPH is particularly noted for its rigidity and crystalline structure, which makes it a widely utilized general-purpose grade in various industries.

PP HOMO grades

GRADE PRODUCER MFR DENSITY DATASHEET
ZH550J NAVID ZAR CHIMI 3.2 download
ZH525J NAVID ZAR CHIMI 3.1 download
ZH515MA NAVID ZAR CHIMI 9 download
ZH520J NAVID ZAR CHIMI 3.1 download
ZH510L NAVID ZAR CHIMI 6 download
502N ARAK 12 download
ZH552R NAVID ZAR CHIMI 25 download
1001M REGAL 8 download
1001P REGAL 15 download
1002G REGAL 0.9 download
1002H REGAL 2 download
1040K REGAL 3.4 download
1002N REGAL 11 download
1002L REGAL 6 download
5655 REGAL 38 download
1040 RC REGAL 23 download
1084K REGAL 3.4 0.91 download
1100H REGAL 2 download
1100L REGAL 6 download
1100N REGAL 12 download
1100RC REGAL 23 download
1100UC REGAL 75 download
1100VC REGAL 120 download
1101M REGAL 9 download
1101P REGAL 15.5 download
1101R REGAL 20 download
1101RC REGAL 22 download
1101SC REGAL 35 download
1148TC REGAL 53 download
1148RC REGAL 22 download
1150N REGAL 11 download
1184L REGAL 6 download
1191N REGAL 11 download
1191XN REGAL 13 download
1150RC REGAL 22 download
1148UC REGAL 75 download
C30S MARUN 6 0.9 download
F30S MARUN 12 0.9 download
HOMOPOLYMER30 POLYNAR 2-3/5 0.9 download
HD 550 J JAM 3.2 0.9 download
HD 552 R JAM 25 0.9 download
HP 510L JAM 6 0.9 download
HP 564S JAM 42 0.9 download
PL-110 POLYNAR 10/5-14 0.9 download
HP 525 J JAM 3 0.91 download
PFI-160 POLYNAR 14-17 0.9 download
PPH-HD-225 TABRIZ 4/5 0.9 download
GRADE PRODUCER MFR DENSITY DATASHEET
PPH-XD-045 TABRIZ 4/5 0.9 download
P-CR-380 POLYNAR 36-40 0.9 download
P-YI-180 POLYNAR 17-20 0.9 download
P-SIF-010 POLYNAR 0/5-2 0.9 download
P-YL-250 POLYNAR 24-26 0.9 download
P-YL-300 POLYNAR 28-32 0.9 download
P-SF-060 POLYNAR 5-7/5 0.9 download
P-YL-350 POLYNAR 32-36 0.9 download
Q30P 0/7 0.9 download
V30S ARAK 18 0.9 download
V30G MARUN 16 0.9 download
V795 MARUN 21 0.9 download
X30G MARUN 9 0.9 download
Z30G MARUN 25 0.9 download
Z30S MARUN 25 0.9 download

What is  Polypropylene (PPH)

Definition Polypropylene, also known as polypropene, is a thermoplastic polymer used in various applications. It is produced from the monomer propylene.
Production Method It is produced via chain-growth polymerization.
Chemical Properties Polypropylene is partially crystalline and nonpolar. It has properties similar to polyethylene but is slightly harder and more heat-resistant.
Material Characteristics It is a white, mechanically rugged material with high chemical resistance.
Bio-Based Counterpart Bio-PP is the bio-based counterpart of polypropylene.
Industry Ranking Polypropylene is the second-most widely produced commodity plastic after polyethylene.

Comparison with Other Types of Polypropylene (PPC)

Polypropylene Homopolymer (PPH)

Polypropylene Homopolymer (PPH) is a form of polypropylene made entirely from propylene monomer units. This means that all the polymer chains in PPH are composed of the same monomer unit, propylene.

Properties: PPH is distinguished by its high stiffness, strength, and strength-to-weight ratio. Additionally, it has excellent weldability and chemical resistance, which makes it appropriate for a variety of corrosion-resistant structures. It is the material of choice for demanding applications because of its higher operating temperature and tensile strength when compared to other plastics like polyethylene.

Applications: PPH is widely utilized in applications requiring high-performance materials, such as industrial machinery parts, medical devices, and automotive components, because of its robustness and endurance.

Polypropylene Copolymer (PPC)

Polypropylene Copolymer (PPC) differs from PPH in that it contains two different monomer units in its polymer chain. Typically, PPC consists of propylene and ethylene monomers.

Properties: PPC is softer but provides better impact strength and durability than PPH, which is stiffer and stronger. In comparison to PPH, it also exhibits better low-temperature toughness and stress crack resistance. Because of these qualities, PPC can be used in situations where impact resistance and flexibility are more important than maximum strength.

Applications: Polypropylene (PPC) is frequently utilized in products that need to strike a compromise between toughness and flexibility, like fibers, packaging films, and injection-molded goods where impact resistance is crucial.

Key Characteristics of PPH

  • Chemical Resistance

Polypropylene Homopolymer (PPH) exhibits excellent chemical resistance, making it suitable for various applications. It does not react with diluted bases and acids, which allows it to be used in containers for cleaning agents, medical products, and other chemically sensitive materials. Additionally, PPH shows outstanding resistance to water and inorganic environments, with minimal weight increase even after prolonged exposure at elevated temperatures. However, it is less resistant to strong oxidizing agents and some organic chemicals, which may cause changes in its properties depending on the extent of absorption and the environmental conditions.

  • Elasticity and Durability

Its high elasticity and durability characterize PPH. The material’s ability to withstand pressure and stress without breaking contributes significantly to its utility in various applications. This resilience is evident in its performance under bending, flexing, and torsion conditions, where PPH retains its shape and integrity. The inherent toughness of PPH, as defined by its ability to deform without early breaking, further underscores its durability and suitability for demanding applications.

  • Resistance to Fatigue

PPH is a material that can endure significant stress without damage, making it ideal for applications where the material is subjected to repeated loading. This endurance, as indicated by its endurance limit and fatigue crack propagation behavior, is particularly valuable in automotive and industrial applications, providing reassurance about its long-term performance and reliability.

  • Insulation Properties

PPH is an excellent insulator in electrical applications due to its high electrical resistance. This property is crucial as it prevents unwanted electrical conductivity, making it a secure choice for electronic devices. The material’s insulating capability is further enhanced by its availability in both transparent and opaque forms, catering to different aesthetic and functional requirements regarding light transmission .

  • Transmissivity

Transmissivity is a notable feature of PPH, particularly relevant in applications requiring light transfer through the material. While generally produced with an opaque appearance, PPH can also be manufactured transparently to meet specific needs related to light transmission. This versatility makes it suitable for various applications, ranging from consumer goods to specialized industrial components.

Applications of PPH in Various Industries

  • Automotive Industry

Polypropylene homopolymer (PPH) is extensively utilized in the automotive industry for components such as dashboards, door panels, and instrument clusters. Its attributes, including good dimensional stability, low moisture absorption, and superior heat resistance, make it particularly suitable for high-temperature environments within vehicles.

  • Electronics

In electronics, PPH’s high electrical resistance makes it an excellent choice for insulating materials in electronic devices. This property prevents unwanted electrical conductivity, which is crucial for the reliable functioning of electronic components.

  • Chemical Storage

PPH materials are prominently used to construct storage tanks and pipes intended for transporting corrosive chemicals or water. Their robustness is due to excellent chemical resistance, thermal stability, and impact resistance, which are essential qualities for enduring harsh industrial environments.

  • Consumer Goods

The consumer goods sector benefits significantly from using PPH, particularly in furniture, toys, and storage containers. The material’s wear and tear resistance, low moisture absorption, and good thermal stability make it ideal for use in home environments. Moreover, PPH is commonly used for food packaging, attributed to its high-temperature resistance, biocompatibility, and excellent barrier properties, which are also advantageous for reducing shipping and transportation costs.

Material Properties of PPH

  • Physical Properties

Polypropylene homopolymer (PPH) is characterized by its density ranging from 0.904 to 0.908 g/cm³, which indicates its lightweight nature. It exhibits minimal water absorption, with a rate of only 0.01% after 24 hours, ensuring its performance in environments where moisture resistance is crucial. The material’s surface is hard and smooth, which reduces the potential for bacterial growth, making it suitable for medical and food contact applications.

  • Mechanical Properties

PPH’s high tensile strength, typically around 4,800 PSI, and flexural strength of 7,000 PSI, make it a reliable choice for applications that require mechanical stress resistance. Its tensile modulus of around 195,000 PSI indicates a high degree of stiffness and rigidity, crucial for structural applications. The material’s impact resistance, quantified by an Izod impact value of 1.9 ft-lb/in and a Rockwell hardness rating of R92, ensures durability in demanding environments.

  • Thermal Properties

The thermal properties of PPH are significant for applications involving varying temperatures. Its melting point is approximately 327°F, which supports its use in high-temperature environments. Its heat deflection temperature at 264 psi is 125°F, and it can continuously operate at temperatures up to 180°F. The coefficient of thermal expansion for PPH is 6.2 x 10^-5/°F, which is important for applications that involve thermal cycling.

  • Electrical Properties

PPH also exhibits excellent electrical properties, which is crucial for its use in electrical and electronic applications. It has a high dielectric strength, typically ranging from 500 to 660 volts/mil, which ensures good insulation characteristics. The material’s volume resistivity is exceptionally high at 8.5 x 10^14 ohm-cm, providing effective resistance to electrical conductivity. PPH has a low dissipation factor at 1 kHz, ranging from 0.0005 to 0.0018, indicating low energy loss at high frequencies, making it suitable for various electronic components.

Conclusion

Polypropylene homopolymer is a widely used general-purpose grade of polypropylene, consisting solely of propylene monomers in a semi-crystalline form. It features a density of 0.904-0.908 g/cm³ and offers good chemical resistance to various substances, though it is less resistant to aromatic and halogenated hydrocarbons and oxidizing agents. It retains mechanical and electrical properties in elevated temperatures and humid conditions, is water-repellent, and resists environmental stress cracking, though it is sensitive to microbial attacks. Applications include packaging, textiles, healthcare products, pipes, automotive components, and electrical applications. Compared to PP copolymers, it is stiffer with a higher strength-to-weight ratio but has lower impact strength and stress crack resistance at low temperatures.