Acrylonitrile Butadiene Styrene (ABS) is a highly versatile thermoplastic polymer widely used in various industrial and consumer applications. This robust material is renowned for its exceptional impact resistance, rigidity, and ease of processing. ABS combines the strength and rigidity of acrylonitrile and styrene polymers with the toughness and elasticity of polybutadiene rubber, resulting in a material with remarkable properties.

ABS GRADES

GRADE PRODUCER MFR DENSITY DATASHEET
F232 JAM 14 1.04 download
F332 JAM 14 1.04 download
P30 JAM 1.04 download
T161B JAM 1.04 download
L322 JAM 23 1.04 download
T6306 JAM 1.04 download
B432 JAM 4 1.04 download
T6 302 JAM 1.04 download
B183 JAM 1.04 download
BR 245 JAM 1.04 download
B532/E JAM 5 1.04 download
C442 JAM 6 1.04 download
BR 277 JAM 1.04 download
B732/E JAM 4.5 1.04 download
E332 JAM 10 1.04 download
SD0150 TABRIZ 1.8 600 download
D232/M3 JAM 8 0.04 download

What is ABS?

 

Acrylonitrile butadiene styrene is an amorphous terpolymer composed of monomers: acrylonitrile, butadiene, and styrene. These monomers are combined in different proportions to achieve the desired properties of the final product. The typical composition ranges from 15% to 35% acrylonitrile, 5% to 30% butadiene, and 40% to 60% styrene.

Composition Terpolymer made by polymerizing styrene and acrylonitrile in the presence of polybutadiene
Glass Transition Temperature Approximately 105°C (221°F)
Melting Point Amorphous, no true melting point
Chemical Resistance Good resistance to concentrated and dilute acids, excellent against alkalis, poor resistance to alcohols, aldehydes, aromatic hydrocarbons, esters, halogenated hydrocarbons, ketones
Use Temperature Range Can be used between -20 and 80°C (-4 and 176°F)
Properties Stronger than pure polystyrene due to nitrile groups binding chains together, contributes chemical resistance, fatigue resistance, hardness, rigidity, and increases heat deflection temperature

Composition and Structure

  1. ABS is a terpolymer polymerizing monomers of acrylonitrile, butadiene, and styrene.
  2. The acrylonitrile component provides chemical resistance, rigidity, and heat stability.
  3. The butadiene component contributes toughness, flexibility, and impact resistance.
  4. The styrene component provides surface hardness, rigidity, and processability.
  5. It has an amorphous structure with crisscrossed chains of polybutadiene and polystyrene-co-acrylonitrile.

Properties and Characteristics of ABS

 

ABS Mechanical Properties

Mechanical Properties

Property Typical Value
Tensile Strength 45-55 MPa (6,500-8,000 psi)
Yield Strength 35-40 MPa (5,100-5,800 psi)
Flexural Strength 70-90 MPa (10,200-13,050 psi)
Impact Strength 15-50 kJ/m² (1.4-4.7 ft-lb/in³)
Elongation at Break 2-20%
Hardness (Shore D Scale) 80-85
Density 1.05-1.07 g/cm³ (0.038-0.039 lb/in³)
Thermal Conductivity 0.2 W/(m·K) (0.036 BTU/(ft·h·°F))
Melting Point 105-110°C (221-230°F)
Glass Transition Point 105°C (221°F)
  • High impact strength, especially at low temperatures
  • Excellent rigidity and dimensional stability
  • Good flexural strength and tensile strength
  • Moderate hardness and abrasion resistance
ABS Mechanical Properties

Mechanical Properties

Property Typical Value
Tensile Strength 45-55 MPa (6,500-8,000 psi)
Yield Strength 35-40 MPa (5,100-5,800 psi)
Flexural Strength 70-90 MPa (10,200-13,050 psi)
Impact Strength 15-50 kJ/m² (1.4-4.7 ft-lb/in³)
Elongation at Break 2-20%
Hardness (Shore D Scale) 80-85
Density 1.05-1.07 g/cm³ (0.038-0.039 lb/in³)
Thermal Conductivity 0.2 W/(m·K) (0.036 BTU/(ft·h·°F))
Melting Point 105-110°C (221-230°F)
Glass Transition Point 105°C (221°F)
  • Heat resistance up to 80-90°C (176-194°F)
  • Low thermal conductivity
  • Good thermoforming and injection molding capabilities
ABS Chemical Properties

Chemical Properties

Property Description
Chemical Formula (C8H12)n
Molecular Weight ca. 210 g/mol
Density 1.05-1.07 g/cm³
Melting Point 105-110°C
Boiling Point 300°C (572°F)
Solubility in Water Little to none
Resistance to Chemicals Good resistance to many chemicals, especially oils and fats
Flammability Combustible; flammable when exposed to open flame
Decomposition Temperature Approximately 400°C (752°F)
  • resistant to acids, alkalies, and concentrated hydrochloric acid
  • Moderate resistance to organic solvents and oils
  • Susceptible to stress cracking in the presence of certain solvents
ABS Thermal Properties

Thermal Properties

Property Value
Thermal Conductivity 0.2 W/(m·K) (0.036 BTU/(ft·h·°F))
Specific Heat Capacity 1.9 kJ/kg·K (0.45 BTU/lb·°F)
Coefficient of Linear Expansion 60-70 x 10^-6 /°C (32-39 x 10^-6 /°F)
Heat Distortion Temperature 95°C (203°F)
Deflection Temperature Under Load 65-85°C (149-185°F)
Flame Retardancy Rating V-2 (UL94 Vertical Burning Test)
  • Good insulating properties
  • Moderate dielectric strength
  • Suitable for electrical housings and enclosures

Applications of ABS

  • Automotive Parts

It is widely used in the automotive industry for interior and exterior components such as Dashboards, instrument panels, door panels, trim, grilles, mirror housings, and interior consoles. Its impact resistance, strength, and lightweight properties make it a preferred choice.

  • Consumer Electronics and Household Appliances

It is commonly used for consumer electronics housings, casings, and components, such as Computer keyboards, mice, remote controls, phone cases, and audio/video equipment. It is also used for household appliances like vacuum cleaners, blenders, coffee makers, etc.  Key attributes are impact resistance, electrical insulation, and ease of molding.

  • Pipes and Fittings

It is used for piping and fittings in commercial and residential plumbing systems, especially drain, waste, and vent (DWV) applications. Benefits include corrosion resistance, ease of installation, and durability.

  • Toys and Sports Equipment

Due to its impact resistance and ability to be molded into complex shapes, it is suitable for toys, games, and sports/recreation equipment. Examples include helmets, protective gear, athletic equipment, skateboards, and bicycles.

  • 3D Printing and Rapid Prototyping

Due to its strength, durability, and processability, this is one of the most popular materials for 3D printing and rapid prototyping. It is widely used to create functional prototypes, models, and small-batch production parts.

  • Medical Devices and Equipment

Its durability, chemical resistance, and ease of sterilization make it suitable for medical instrument housings, equipment casings, laboratory equipment, and disposable medical devices.

This material is used in many industries, from automotive and consumer goods to medical devices and 3D printing. Its balanced mechanical, thermal, and processing properties make it popular for engineering needs.

Manufacturing of ABS

ABS plastic parts can be produced using various manufacturing processes. The ideal production method is influenced by the quantity needed, geometry, and the desired properties of your part. Here are some standard methods:

1. Injection Molding

Injection molding is the most common process for manufacturing ABS plastic parts. It involves feeding ABS resin pellets into a hopper, melting them under high pressure, and injecting molten plastic into a mold.

Advantages:

  • Produces less waste
  • Manufactures large volumes of components with high accuracy
  • Produces complex and multi-featured parts
  • Enhances mechanical strength and durability of manufactured parts
  • Low labor costs due to automation

2. CNC Machining

CNC machining involves using computer numerical control (CNC) milling or turning machines to machine ABS plastic parts. This method is suitable for producing low-volume or customized ABS parts with tight tolerances.

Advantages:

  • High precision and accuracy
  • Ideal for complex geometries and intricate details
  • Can produce parts with tight tolerances

3. 3D Printing

ABS plastic is a popular material for 3D Printing, especially with FDM (Fused Deposition Modeling) 3D printers. This method allows for producing complex geometries and prototypes with relatively low setup costs compared to traditional processes like injection molding.

Advantages:

  • Produces complex geometries and prototypes
  • Relatively low setup costs
  • Can produce parts with intricate details

4. Extrusion

ABS can be extruded to create continuous profiles, such as tubes, rods, and sheets. The extruded ABS can be cut into specific lengths to produce parts.

Advantages:

  • Produces continuous profiles
  • It can be cut into specific lengths

5. Blow Molding

Blow molding is typically used to produce hollow ABS plastic parts, such as bottles, containers, and automotive components. The process involves inflating a molten ABS plastic tube inside a mold cavity, creating the desired shape as it cools and solidifies.

Advantages:

  • Produces hollow parts
  • Can produce complex shapes

6. Thermoforming

Thermoforming is a process used to produce ABS plastic parts from sheets. The ABS plastic sheet is heated until it becomes pliable, then stretched over a mold and cooled to take on the desired shape.

Advantages:

  • Produces parts from sheets
  • Can produce complex shapes

These manufacturing processes offer various advantages and are suitable for different applications. The choice of process depends on the specific requirements of the part being produced.

Conclusion

Acrylonitrile Butadiene Styrene (ABS) is a highly versatile and widely used thermoplastic polymer that offers an exceptional combination of impact resistance, rigidity, dimensional stability, and ease of processing. Its diverse applications span various industries, including automotive, consumer products, construction, and electronics. Despite its limitations, ABS’s unique properties and, importantly, its cost-effectiveness, make it a popular choice for numerous applications requiring durability, strength, and versatility. This reassures its value in industries where cost-effectiveness is a key consideration.